Page 3 - SD 2507
P. 3

General corrosion

                                      SD 2507 grade performs nearly as well as highly alloyed austenitic stainless steels
                                      in most of inorganic acids. For sulphuric acid solutions, copper containing, super-
                                      duplex grades should be prefered.

                                       SD 2507 is suitable for uses in organic acids including high concen-trations and
                                      temperatures where austenitic stainless steels corrode at a higher rate.

                                                                              Corrosion rate
                                             Boiling curve
                                                                                 (mdd)
                                          100                       212          80                  White liquor :
                                                CLI-SAF 2507                     70                 NaOH  :  125  g/l
                                                                                                    Na 2S  :  50  g/ll
                                                                                 60                 Na 2/So 4  :  16  g/l
                                          80
                                                                    176
                                         Temperature (°C)   60   S32520   140   Temperature (°F)   40   304L   Sulfidity  :  21  %
                                                                                 50
                                                                                                    Na 2CO 3  :  27  g/l
                                                                                                    H2S bubbling
                                                                                 30 316L
                                                                                 20
                                              N08904
                                              N08926
                                                                                 10     UR 45N
                                          40   316                  104          0               CLI/SAF 2507
                                                     S31803                          20 40 60 80 100
                                                                316                   Chloride concentration (g/l)
                                          20                         68          Heat transfer (solution 140°C - Sample 80°C)
                                            0   20   40   60   80   100                Pulp and Paper industry
                                                      H 2 SO 4  (% wt)        Corrosion rate versus chloride content in Kraft media


                                            Medium : NaCl 30g/l + Fe 2  (SO 4 )3 0,1 % - pH = 2 aerated   Chloride
                                                 T = 60°C Test duration 15 days   concentration (ppm)
                                        Corrrosion rate
                                          (mdd)                                  2000   CLI-SAF 2507

                                          3  00                0 ppm F   -       1600
                                                              1000 ppm F   -         UR B6
                                                                                 1200   UR 45N
                                          2  00
                                                                                 800   317 LNM
                                                                                     317 LN
                                                                                     316 LN
                                          1  00                                       316L
                                                                                 400
                                                                  No
                                          0                      Corrosion           20    60    80    120   (°C)
                                              316L 317LNM UR45N   N08904 SD 2507     68    140   176   216   (°F)
                                                Pollution control equipments

                                        Effects of fluoride contents on the uniform corrosion rate   Safe use limits of stainless steels versus
                                                                                  chloride content and temperature in 54 % P205

                                       mm/year (mpy)
                                        0.25(10)   50% acetic acid             °C /°F
                                         0.20(8)                                        Boiling point curve
                                                     AISI   AISI   Test time     120/250
                                                     316L
                                                           317L
                                                                1+ 3+ 3 days
                                         0.15(6)                              100/210
                                                                                           SD 2507
                                         0.10(4)         UR B28                80/175   UR B28
                                                              SD 2205
                                           0.05(2)                             60/140    AISI
                                                                                    316L
                                                             SD 2507
                                             0             No attack           30/ 85
                                                                 25
                                              0   5   10   15   20   HCOOH, weight %   1   2   3   4   % HCl
                                        Corrosion rate in boiling mixtures of 50% acetic acid   Isocorrosion diagram in hydrochloric acid
                                                                                  Corrosion rate of 0.1mm/year (4mpy)
                                             and varying proportions of formic acid   in stagnant test solution



                                            Pitting and crevice corrosion
                                      The minimum PREN value ( [%Cr] + 3.3[% Mo] +  16[%N]  ) of  40 also explains
                                      why the alloy is highly resistant to pitting and crevice corrosion. The alloy behaves
                                      much better than 904L and is, for pitting corrosion resistance, nearly equivalent to
                                      6  Mo  super  g  grade.  In  some  cases,  the  crevice  corrosion  resistance  is  slightly
                                      higher than 6 Mo alloys due to the 25% Cr additions.
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