Page 3 - SA 316
P. 3

Temperature °C    Temperature °F   Temperature °C           Temperature °F
                                                                         160       Risk of SCC   904L
                                           Boiling
                                                                         140
                                        100                       212    120                              248
                                                                         100              304L/ 316L      212
                                                                          80                              176
                                        80                        176     60                              140
                                                                          40                Solubility
                                                                          20                              68
                                        60                        140       0    20    40    60    80   100
                                                    904L                                          NaOH, weight %
                                             316L
                                        40                        104
                                          304L                           Fig 4 – Isocorrosion diagram 0.1 mm/year, in sodium
                                                                        hydroxide.
                                        20  0   20   40   60   80 100   68
                                                                         Temperature °C           Temperature °F
                                                                         160                              320
                                                                         140                              284
                                      Broken line curve represents the boiling point   120                248
                                                                         100                              212
                                         Fig 3 - Isocorosion diagram 0.1 mm/year   80                    176
                                      for  austenitic  stainless  steels  in  natural   60   304L/ 316L   140
                                      aerated sulphuric acid of chemical purity   40   13% Cr steel       104
                                                                          20           40          80   100  68
                                                                           0     20          60   HNO 3 weight %

                                                                          Fig 5 – Isocorrosion diagram 0.1 mm/year, in nitric
                                             Hot forming               cid. Broken line represents the boiling point
         PROCESSING

                                      Hot forming should be carried out in a temperature range of 1150-800° C (2102-
                                      1472°F). If the final forming temperature falls below 950°C ( 1742°F), an annealing
                                      solution (1050-1150°C, 1922-2102 °F) is necessary.
                                      The  cleanliness  of  the  surface  is  very  important  (avoid  oil  contamination).    A
                                      neutral  or  slightly  oxidising  atmosphere  is  required.  Due  to  the  low  thermal
                                      conductivity,  the  holding  time  of  temperature  may  be  longer  than    for  a  carbon
                                      steel
                                      ( 50%). Quenching must be done fastly after forming.
                                            Cold forming
                                      The alloy can be cold formed without any problem. The cold hardening of the steel
                                      explains why it may require more powerfull equipments than for a structural steel.
                                      Molybdenum  bearing  implies  also  some  more  powerfull  equipments  than  Cr-Ni
                                      austenitic stainless steels.
                                            Pickling
                                      A nitro-hydrofluoric acid bath (10-20% HNO 3  – 1,5-5% HF) at 20-60°C ( 68-142°F)
                                      is used for the picking treatment. A 10-20% H 2 S0 4  – 1,5-5% HF pickling bath may
                                      also be used. Passivation- decontamination treatments may be performed with a
                                      10-20% weight nitric acid solution.
                                            Cutting
                                       Thermal cutting (plasma, thermal sawing…). After cutting pickling or grinding are
                                       necessary to eliminate the oxide formed layer.

                                       Mechanical cutting (shearing, stamping, cold sawing…).
                                            Welding
                                      The  alloy  can  be  easy  welded  without  hot  cracking  phenomenon,  using  an
                                      adequate filler  metal  (from  5  to  15%   ferrite).  The  alloy  is  not  sensitive  to  cold
                                      cracking  phenomenon.  All  welding  processes  can  be  used  including  filler
                                      processes.
                                             Filler material
                                          Electrode E316L-15 or E316L-16 (ASME Sect II – Part C SFA5-4)
                                          Wire     ER 316L (ASME Sect II - Part C SFA 5-9)
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