Page 5 - SD 2507Cu
P. 5

Stress corrosion cracking resistance

                                      The stress corrosion resistance properties of SD 2507Cu is excellent in high
                                      temperature chloride containing solutions as well as in sour gas applications.


         FABRICATION
                                              °C              °F               MPa                     Rp 0.2 %
                                           300             SD 2507Cu570                                Stress threshold
                                                          Super duplex         500
                                                          No cracking
                                                                               400
                                           200                 390
                                                        UR 45N
                                                                               300
                                                    UR 35N
                                                                               200
                                           100                 210
                                                     AISI 304/316              100

                                                                                0
                                                               32

                                             0     0.001   0.1   10 Cl  (%)         304L 316L UR52N 904L
                                                                 -
                                              Constant-strain tests in autoclave     Stress corrosion cracking in chloride media :
                                               Above the curve, SCC occurs.          300 g/l NaCl - T = 110°C - pH = 1
                                         Open circles means no SCC for UNS 32550/UR 52N +    Threshold stress without crack after 1 month
                                                                                 Chloride (mg/l)
                                                  Austenitic   Duplex        1000000         MR 01-75 limits
                                         SCC   316L 170 HE URB6 UR45N UR47N UR52N
                                        resistance                                           for 22 Cr and 25 Cr duplex

                                            10                                100000                 CRACKING
                                                                                         CRACKING
                                                                                                S 32550
                                            20                                       S 31803
                                                                                     UR 45N     UR 52N +   NO
                                                                                                 CRACKING
                                            30                                10000   NO CRACKING

                                            40
                                           Loss of ductility
                                                                               1000
                                                                                 0.01   0.1  Hydrogen Sulphide (psi)  10   100
                                                                                               1
                                                      -6
                                        Slow strain rate tests (10 /sec) in NaCl, 40% pH=2 (HCl),
                                       110°C - Elongation in air - Elongation in corrosive medium   Suggested limits for Duplex
                                                                                     and Super duplex stainless steels

                                            Cold forming

                                      Due to its higher mechanical properties, the cold forming of SD 2507Cu requires
                                      more strength than austenitic grades. For cold deformations higher than 20 %, an
                                      intermediate heat treatment is required (solution annealing 1080/1120°C
                                      (1976/2018°F) + water cooling).

                                      Detailed guidelines for cold forming of unwelded and welded plates are available
                                      upon request.

                                            Hot forming

                                      Between 1150°C and 1000°C ( 2102 and 1832°F). After hot forming, a new solution
                                      annealing heat treatment in the range 1080/1120°C ( 1976/2018°F) + water cooling
                                      is necessary.

                                            Pickling

                                      Same conditions as for 316L grade, but the pickling time is at least twice that of
                                      316L  grade.  An  increase  of  the  temperature  of  the  pickling  bath  reduces  the
                                      pickling time.
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